全文获取类型
收费全文 | 415篇 |
免费 | 10篇 |
专业分类
化学 | 190篇 |
晶体学 | 2篇 |
力学 | 3篇 |
数学 | 50篇 |
物理学 | 180篇 |
出版年
2022年 | 1篇 |
2021年 | 5篇 |
2020年 | 3篇 |
2019年 | 1篇 |
2018年 | 5篇 |
2017年 | 4篇 |
2016年 | 2篇 |
2015年 | 8篇 |
2014年 | 10篇 |
2013年 | 11篇 |
2012年 | 28篇 |
2011年 | 32篇 |
2010年 | 24篇 |
2009年 | 14篇 |
2008年 | 35篇 |
2007年 | 50篇 |
2006年 | 31篇 |
2005年 | 40篇 |
2004年 | 29篇 |
2003年 | 18篇 |
2002年 | 27篇 |
2001年 | 10篇 |
2000年 | 9篇 |
1999年 | 1篇 |
1998年 | 3篇 |
1996年 | 1篇 |
1995年 | 1篇 |
1994年 | 2篇 |
1993年 | 2篇 |
1992年 | 2篇 |
1991年 | 2篇 |
1990年 | 2篇 |
1989年 | 2篇 |
1985年 | 2篇 |
1982年 | 2篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1976年 | 1篇 |
1974年 | 2篇 |
排序方式: 共有425条查询结果,搜索用时 562 毫秒
101.
Lee HY Ryu S Kang H Jun YW Cheon J 《Chemical communications (Cambridge, England)》2006,(12):1325-1327
Remarkable selectivity is achieved in the cleavage of benzyl ethers using ball-shaped palladium nanocatalysts, Pd@MCM-48, in an MCM-48 matrix. The unique nanocatalysts not only feature unprecedented complete hydrogenolysis selectivity of a benzyl ether over hydrogenation of a double bond, but also demonstrate selective cleavage of unsubstituted benzyl ether over substituted benzyl ethers. 相似文献
102.
Choi JS Jun YW Yeon SI Kim HC Shin JS Cheon J 《Journal of the American Chemical Society》2006,128(50):15982-15983
Hybrid nanoparticles are of significant interest primarily because of their innate multifunctional capabilities. These capabilities can be exploited when hybrid nanoparticles are used for applications in the biomedical sciences in particular, where they are utilized as multimodal nanoplatforms for sensing, imaging, and therapy of biological targets. However, the realization of their biomedical applications has been difficult, in part because of a lack of high quality hybrid nanoparticles which possess high aqueous colloidal stability and biocompatibility while retaining their multifunctionalities. Here, we present the development of inorganic heterodimer nanoparticles of FePt-Au with multifunctional capabilities including catalytic growth effects, magnetic resonance (MR) contrast effects, optical signal enhancing properties, and high colloidal stability and biocompatibility. Their multimodal capabilities for biological detection are demonstrated through their utilizations in the patterned biochip based detection of avidin-biotin interaction as well as in molecular MR imaging of neuroblastoma cells. 相似文献
103.
Kim HS Lee MH Jeong NC Lee SM Rhee BK Yoon KB 《Journal of the American Chemical Society》2006,128(47):15070-15071
Zeolite-intercalated semiconductor quantum dots (QDs) have long been proposed to give very high third-order nonlinear optical (3NLO) responses. However, measurements of their 3NLO responses have not been possible due to the lack of methods to prepare optically transparent QD-incorporating zeolite films supported on optically transparent substrates and to confine QDs only within zeolite interiors. We found that the zeolite-Y films grown on indium-tin-oxide-coated glass plates (Ygs) remain firmly bonded to the substrates during ion exchange with Pb2+ ions, drying, and formation of PbS QDs by treating Pb2+ ions with H2S. A series of Ygs encapsulating different numbers (n = 0, 8, 14, 23, and 33) of PbS in a unit cell [(PbS)n-Yg] were prepared. The PbS QDs were expelled by adsorbed moisture to the external surfaces, and the expelled QDs formed large QDs. Coating of the (PbS)n-Ygs with octadecyltrimethoxysilane results in effective confinement of the QDs within the internal pores. The zeolite-encapsulated PbS QDs showed remarkably high 3NLO activities at 532 and 1064 nm which are unparalleled by other PbS QDs dispersed in other matrixes. 相似文献
104.
Gabyshev N Abe K Abe K Adachi I Aihara H Asano Y Aulchenko V Aushev T Bahinipati S Bakich AM Balagura V Barberio E Bartel W Bay A Bedny I Bitenc U Bizjak I Bondar A Bozek A Bracko M Browder TE Chen A Chen WT Cheon BG Chistov R Choi Y Chuvikov A Cole S Dalseno J Danilov M Dash M Drutskoy A Eidelman S Garmash A Gershon T Gokhroo G Golob B Haba J Hayasaka K Hayashii H Hazumi M Hokuue T Hoshi Y Hou S Hou WS Hsiung YB Ikado K Imoto A Inami K Itoh R Iwasaki M Iwasaki Y Kang JH Kawasaki T Khan HR 《Physical review letters》2006,97(20):202003
We report the first measurements of the doubly charmed baryonic B decays B --> Lambda c+ Lambda c- K. The B+ --> Lambda c+ Lambda c- K+ decay is observed with a branching fraction of (6.5(-0.9)(+1.0)+/-1.1+/-3.4)x10(-4) and a statistical significance of 15.4sigma. The B0 --> Lambda c+ Lambda c- K0 decay is observed with a branching fraction of (7.9(-2.3)(+2.9)+/-1.2+/-4.1)x10(-4) and a statistical significance of 6.6sigma. The branching fraction errors are statistical, systematic, and the error resulting from the uncertainty of the Lambda c+ --> pK- pi+ decay branching fraction. The analysis is based on 357 fb(-1) of data accumulated at the Upsilon(4S) resonance with the Belle detector at the KEKB asymmetric-energy e+ e- collider. 相似文献
105.
Chistov R Abe K Abe K Adachi I Aihara H Anipko D Aulchenko V Aushev T Bakich AM Balagura V Barberio E Bay A Bedny I Belous K Bitenc U Bizjak I Blyth S Bondar A Bozek A Bracko M Brodzicka J Browder TE Chang MC Chao Y Chen A Chen KF Chen WT Cheon BG Choi Y Choi YK Chuvikov A Cole S Dalseno J Danilov M Dash M Dragic J Drutskoy A Eidelman S Epifanov D Gabyshev N Garmash A Gershon T Go A Gokhroo G Golob B Gorisek A Ha H Haba J Hara T Hayasaka K Hayashii H Hazumi M Heffernan D Hokuue T Hoshi Y Hou S 《Physical review letters》2006,97(16):162001
We report the first observation of two charmed strange baryons that decay into Lambda(c)(+)Kappa(-)pi(+). The broader of the two states is measured to have a mass of 2978.5+/-2.1+/-2.0 MeV/c2 and a width of 43.5+/-7.5+/-7.0 MeV/c2. The mass and width of the narrow state are measured to be 3076.7+/-0.9+/-0.5 MeV/c;{2} and 6.2+/-1.2+/-0.8 MeV/c2, respectively. We also perform a search for the isospin partner states that decay into Lambda(c)(+)Kappa(0)/(s)pi(-) and observe a significant signal at the mass of 3082.8+/-1.8+/-1.5 MeV/c2. The data used for this analysis were accumulated at or near the Upsilon(4S) resonance, using the Belle detector at the e+ e- asymmetric-energy collider KEKB. The integrated luminosity of the data sample used is 461.5 fb(-1). 相似文献
106.
Garmash A Abe K Abe K Adachi I Aihara H Asano Y Aushev T Aziz T Bahinipati S Bakich AM Barbero M Bedny I Bitenc U Bizjak I Bondar A Bozek A Bracko M Brodzicka J Browder TE Chang P Chao Y Chen A Chen KF Chen WT Cheon BG Chistov R Choi Y Choi YK Chuvikov A Dalseno J Danilov M Dash M Dragic J Drutskoy A Eidelman S Epifanov D Fratina S Gabyshev N Gershon T Go A Gokhroo G Golob B Gorisek A Ha HC Hara T Hasegawa Y Hastings NC Hayasaka K Hayashii H Hazumi M Hokuue T Hoshi Y Hou S Hou WS Hsiung YB 《Physical review letters》2006,96(25):251803
We report results on a Dalitz analysis of three-body charmless B+/- --> K+/-pi+/-pi+/- decay including searches for direct CP violation. We report the first observation of the decay B+/- --> f2(1270)K+/- with a statistical significance above 6sigma. We also observe first evidence for large direct CP violation in the B+/- --> rho(770)0K+/- channel. The results are obtained with a data sample that contains 386 10(6) BB pairs collected at the Y(4s) resonance with the Belle detector at the KEKB asymmetric-energy e+e- collider. 相似文献
107.
Ishikawa A Abe K Adachi I Aihara H Anipko D Asano Y Aushev T Bakich AM Balagura V Barbero M Bitenc U Bizjak I Blyth S Bondar A Bozek A Bracko M Browder TE Chang P Chao Y Chen A Cheon BG Choi Y Choi YK Chuvikov A Dalseno J Danilov M Dash M Drutskoy A Eidelman S Fratina S Gabyshev N Gershon T Gokhroo G Golob B Gorisek A Ha H Haba J Hara T Hayasaka K Hayashii H Hazumi M Hinz L Hokuue T Hoshi Y Hou S Hou WS Hsiung YB Iijima T Ikado K Inami K Ishino H Itoh R Iwasaki M Iwasaki Y Kang JH Kataoka SU 《Physical review letters》2006,96(25):251801
We report the first measurement of the forward-backward asymmetry and the ratios of Wilson coefficients and in A9/A7 and A10/A7 in B --> K*l+l-, where l represents an electron or a muon. We find evidence for the forward-backward asymmetry with a significance of 3.4sigma. The results are obtained from a data sample containing 386 x 10(6) BB pairs that were collected on the Y(4S) resonance with the Belle detector at the KEKB asymmetric-energy e+e- collider. 相似文献
108.
Geom Seog Seo Jeong Kun Lee Ji In Yu Ki Jung Yun Soo Cheon Chae Suck Chei Choi 《Experimental & molecular medicine》2010,42(2):99-104
Interferons play critical roles in tumor pathogenesis by controlling apoptosis and through cellular anti-proliferative and differentiation activities. Interferon inducible transmembrane protein (IFITM) family genes have been implicated in several cellular processes such as the homotypic cell adhesion functions of IFN and cellular anti-proliferative activities. Expression levels of IFITM genes have been found to be up-regulated in gastric cancer cells and colorectal tumors. IFITM3 (also known as 1-8U) is a member of the IFITM family, and has been described as a key player in specification of germ cell fate. IFITM3 was first isolated from a genetic screen aimed at identifying genes involved in acquisition of germ cell competence. It has been proposed that epiblast cells have the highest expression of IFITM3 initiated germ cell specification and that homotypic association can discriminate germ cells from their somatic neighbors. In an attempt to better understand the genetic influences of IFITM3 on ulcerative colitis, we have identified possible variation sites and single nucleotide polymorphisms (SNPs) through two exons and their boundary IFITM3 intron sequences including the ~2.1 kb promoter regions. To determine whether or not these IFITM3 SNPs are associated with susceptibility to ulcerative colitis, frequencies of the genotype and allele of IFITM3 polymorphisms were analyzed on genomic DNAs isolated from patients with ulcerative colitis and from healthy controls. We also investigated the haplotype frequencies constructed by these SNPs in both groups. In this study, we also showed that expression level of IFITM3 mRNA was significantly higher in tissues of the ileum and cecum of the digestive system. We identified a total of seven SNPs and multiple variation regions in the IFITM3 gene. The genotype frequency of the g.-204T>G polymorphism in patients with ulcerative colitis was significantly different from that of the control group. Our results strongly suggest that polymorphisms of the IFITM3 gene may be associated with susceptibility to ulcerative colitis. 相似文献
109.
110.